Wonders of Unstable Isotopes

Two atoms may have the same number ofMost elements have between two and six stable
protons, and thus be of the same element, yetisotopes. On the other hand, a few elements such
differ in their number of neutrons. Such atomsas technetium have no stable isotopes. Twenty
are called isotopes, atoms of the same elementelements, inclusive of gold, fluorine, sodium,
having different masses. Thus isotopes are atomsaluminum, and phosphorus, have only one stable
of the same element that have different massesisotope each. The element with the most stable
due to differences in the number of neutronsisotopes is easy to remember because its name
they contain. The name comes from the Greekis almost the same as its number of stable
phrase ‘isos topos’, meaning "same place":isotopes such as tin, with 10. As for unstable
because they have the same atomic number,isotopes, there are over 1,000, some of which
isotopes of the same element occupy the sameexist in nature, but most of which have been
position on the periodic table. Because the atomiccreated synthetically in laboratories. This number is
number of any element is established, sometimesnot fixed; in any case, it is not necessarily
isotopes are represented simply with the massimportant, because many of these highly
number, thus: 93Ag. They may also be designatedradioactive isotopes last only for fractions of a
with a subscript notation indicating the number ofsecond before decaying to form a stable isotope.
neutrons, so that this information can be obtainedYet radioisotopes in general have so many uses,
at a glance without having to do the arithmetic.in comparison to stable isotopes, that they are
For the silver isotope shown here, this is writtenoften referred to simply as "isotopes."
as Isotopes can also be indicated by simpleBefore proceeding with a discussion of isotopes
nomenclature: for instance, carbon-12 orand their uses, it is necessary to address a point
carbon-13.raised very often, when it is stated that some
Many isotopes are stable, meaning that they areatoms do have the same numbers of neutrons
not subject to radioactive decay, but many moreand protons. In fact, nuclear stability is in part a
are radioactive. The latter, also known asfunction of neutron-to-proton ratio. Stable nuclei
radioisotopes, play a significant role in modern life.with low atomic numbers (up to about 20) have
Carbon-14, for instance, is used for estimating theapproximately the same number of neutrons and
age of objects within a relatively recent span ofprotons. For example, the most stable and
time—up to about 5,000 years—whereasabundant form of carbon is carbon-12, with six
geologists and other scientists use uranium-238 toprotons and six neutrons. Beyond atomic number
date minerals of an age on a scale with that of20 or so, however, the number of neutrons
the Earth. Concerns over nuclear power andbegins to grow: in other words, the lowest mass
nuclear weapons testing in the atmosphere havenumber is increasingly high in comparison to the
heightened awareness of the dangers posed byatomic number. For example, uranium has an
certain kinds of radioactive isotopes, which canatomic number of 92, but the lowest mass
indeed be hazardous to human life. However, thenumber for a uranium isotope is not 184, or 92
reality is that people are subjected to considerablymultiplied by two; rather it is 218. The ratio of
more radiation from non-nuclear sources.neutrons to protons necessary for a stable
Radioactivity is a term used to describe aisotope creeps upward along the periodic table: for
phenomenon whereby certain materials areexample, tin with an atomic number of 50, has a
subject to a form of decay brought about by thestable isotope with a mass number of 120,
emission of high-energy particles or radiation.indicating a 1.4 to 1 ratio of neutrons to protons.
Forms of particles or energy emitted in radiationFor mercury-200, this ratio is 1.5 to 1.
include alpha particles (positively charged heliumBy definition the higher is the atomic number the
nuclei); beta particles (either electrons orgreater is the number of protons in the nucleus.
subatomic particles called positrons); or gammaThis means that more neutrons are required to
rays, which occupy the highest energy level in the"bind" the nucleus together. In fact, all nuclei with
electromagnetic radiation emitted by the Sun.84 protons or more (i.e., starting at polonium and
Radioactivity will be discussed below, but for themoving along the periodic table) are radioactive,
present, the principal concern is with radioactivefor the simple reason that it is increasingly difficult
properties as a distinguishing factor between thefor the neutrons to withstand the strain of
two varieties of isotope. Isotopes are eitherkeeping so many protons in place. One can predict
stable or unstable. The unstable variety, known asthe mode of radioactive decay by noting whether
radioisotopes, is subject to radioactive decay, butthe nucleus is neutron-rich or neutron-poor. While
in this context, "decay" does not mean what itneutron-rich nuclei undergo beta emission, which
usually does. A radioisotope does not "rot"; itdecreases the numbers of protons in the nucleus,
decays by turning into another isotope of theneutron-poor nuclei typically undergo positron
same element or even into another elementemission or electron capture, the first of these
entirely. (For example, uranium-238 decays bybeing more prevalent among the lighter nuclei.
emitting alpha particles, ultimately becomingElements with atomic numbers of 84 or greater
lead-206.) A stable isotope, on the other hand, hasgenerally undergo alpha emission, which decreases
already become what it is going to be, and will notthe numbers of protons and neutrons by two
experience further decay.each.