| Molybdenum plays a more vital role in the global | | | | possibly the United States). |
| nuclear renaissance than you might suspect. | | | | Existing reactors along coastal areas in Asian |
| Without the silvery white metal, the world's | | | | countries presently breaks down as follows: Japan |
| energy infrastructure would somewhat suffer. | | | | (57), South Korea (26), China and Taiwan (19) and |
| But, nuclear power plants would be set back at | | | | India (11). Because these are the most prone to |
| least two decades. The new high performance | | | | seawater or brackish corrosion, they are also the |
| stainless steels (HPSS) contain as much as 7.5 | | | | likely candidates for upgrading existing condenser |
| percent molybdenum and can add more than | | | | tubing to high alloy stainless steel. And their new |
| three times the life to the world's aging nuclear | | | | reactors are likely going to be constructed along |
| fleet condenser tubes. | | | | their coasts, requiring the super austenitic grades. |
| During the early construction of nuclear power | | | | As an aside, of the previously mentioned 190 |
| plants, steam condensers relied upon copper base | | | | nuclear power plants which had replaced their |
| alloys - brass and copper nickel - for heat transfer | | | | condensers with HPSS, 45 percent used fresh |
| capabilities. These alloys have high coefficients of | | | | water as coolant. Those plants chose the high |
| thermal conductivity required in steam generation | | | | alloy steel as a 'fail-safe' measure to prevent |
| to power nuclear reactor turbines. But | | | | interrupted service or a potential reactor incident. |
| copper-alloyed tubes were being replaced too | | | | The United Nations estimates that two-thirds of |
| quickly - with an average life of eight years - | | | | the planet's population will be living with water |
| because of sulphide pitting. Hardest hit were those | | | | stress by 2025. Global freshwater scarcity may |
| reactors using polluted seawater to cool their | | | | demand the use of brackish or seawater as |
| reactors. | | | | nuclear reactor coolant. To prevent the |
| Over the past 30 years ago, nuclear utilities slowly | | | | accompanying corrosion, the higher-percentage |
| began turning to the super austenitic stainless | | | | molybdenum alloy, specifically the 654 SMO(R), |
| steels as one way to make their nuclear reactors | | | | could emerge as the condenser tubing material of |
| last longer. The addition of molybdenum, initially | | | | choice. Either the 254 SMO(R) or the 654 would |
| starting with percentage of less than four | | | | be utilized in desalination plants required to |
| percent, helped increase the thermal conductivity | | | | overcome water shortages in the hardest hit |
| lacking in nickel, iron or steel. At nuclear stations | | | | areas: North Africa, the Middle East and West |
| which replaced the copper alloys with HPSS | | | | Asia. |
| condenser tubes, 57 percent rated the thermal | | | | Typically, nuclear power plant condenser tubing |
| performance good and all but one rated it normal. | | | | requires approximately 520,000 feet of stainless |
| Molybdenum had helped overcome the thermal | | | | steel. According to the International Molybdenum |
| hurdle. | | | | Association (IMOA), larger reactors could utilize up |
| A large number of the 190 nuclear reactors, | | | | to one million feet of stainless steel. With the |
| which now utilize HPSS condenser tubes, reported | | | | higher molybdenum grades found in the super |
| an average life in excess of 18 years. The longest | | | | alloys, new nuclear reactors could require tens of |
| stainless steel condenser installation has remained | | | | thousands of metric tons of molybdenum. |
| in service more than 26 years, according to a | | | | By comparison, nuclear waste containers |
| study done several years ago. According to a | | | | proposed for the Yucca Mountain nuclear waste |
| report published in 2000, more than 100 million | | | | repository were forecast to consume about |
| feet of super-alloy stainless steel tubes have | | | | 15,000 metric tons of moly. While this project |
| replaced the older, copper-alloy tubing. | | | | may or may not proceed as planned to the |
| Condensers are large heat exchangers used in | | | | construction phase, the Nuclear Energy Institute |
| nuclear power plants. Condensers have thousands | | | | (NEI) has proposed regionalized storage of spent |
| of tubes horizontally mounted to condense and | | | | fuel. |
| recover the steam passing through turbines. Each | | | | Should comparably designed storage canisters be |
| low-pressure turbine generally has a condenser, | | | | utilized to 'temporarily' contain the nuclear waste, |
| which also maintains a vacuum to optimize the | | | | it is likely molybdenum will play a key role. |
| turbine's efficiency. | | | | According to the U.S. Government's Energy |
| Water fouling deposits were cited as a major | | | | Citation Database, as published by the |
| problem at many reactors, especially with | | | | Department of Energy's Office of Scientific and |
| condenser tubes where seawater or high-chloride | | | | Technical Information, "Alloys with combined |
| brackish water was the coolant. Pitting corrosion, | | | | chromium plus molybdenum contents greater than |
| tube sheet crevice corrosion and galvanic | | | | 30 percent were the most resistant to general |
| corrosion put the tubes at risk for leakage. | | | | and local attack." This was the conclusion reached |
| Plugging, mud, or detritus accumulating in | | | | after corrosion scouring tests were performed on |
| condenser tubes reduce a power plant's efficiency. | | | | stainless steel and nickel-based alloys to immobilize |
| Utilities use cleaning systems with small, abrasive | | | | high-level, radioactive waste. |
| sponge-like balls to keep the tubes clean and test | | | | Another aspect where high-percentage |
| for tube defectives with probing devices. Tube | | | | molybdenum stainless steel would double up is |
| thinning and corrosion create the opportunity for | | | | with the expansion of nuclear desalination plants. In |
| tube leakage. This can not be tolerated because | | | | the past, and in our publication, "Investing in the |
| chemicals such as sodium and chlorides find their | | | | Great Uranium Bull Market," we have discussed |
| way into the reactor vessel or steam generator. | | | | the rise of nuclear desalination across those |
| Upgrading the steam condenser tubing to stainless | | | | coastal areas, requiring far more freshwater than |
| steel also plays a vital role in the 'power uprate' | | | | can possibly be transported through other means. |
| program utilities have used to increase generating | | | | The World Nuclear Association (WNA) has |
| capacity for existing reactors as we recently | | | | reported of numerous such desalination projects |
| discussed. The more advanced uprate program | | | | in progress. |
| could add up to 20-percent capacity to existing | | | | Will The Energy Bull Have Sufficient Moly? |
| U.S. nuclear reactors. | | | | From nearly every energy project - oil, gas, coal |
| Different Molybdenum Alloys | | | | and nuclear, and for water, molybdenum demand |
| There are several HPSS manufacturers for | | | | will continue increasing. Super austenitic grades |
| nuclear reactor condensers. The most prominent | | | | demand a higher moly content to combat |
| in the nuclear sector include Pennsylvania-based | | | | corrosion and provide reliability of service. Of |
| ATI Allegheny Ludlum and Finland's Outokumpu. | | | | course, there will be substitution in the face of |
| Each offers austenitic steels with chromium and | | | | future supply shortfalls. In some instances, there |
| nickel composition of between 20 and 25 percent | | | | are reports the Russians have substituted |
| for each alloy and a range of 6.2 to 7.5 percent | | | | vanadium for molybdenum in some of their oil and |
| molybdenum. | | | | gas pipelines to conserve on moly consumption. |
| In a paper presented by Jan Olsson of Avesta | | | | ATI Allegheny Ludlum has argued for the |
| Sheffield (before the company was acquired by | | | | substitution of two-percent manganese for every |
| Outokumpu), he highlighted the results of tests | | | | percent of nickel, but in the lower grade austenitic |
| performed on the new super-austenitic stainless | | | | groups which do not demand the corrosion |
| steel, 654 SMO(R). Metals comprising this brand | | | | resistance of energy projects. |
| include 25-percent chromium, 22-percent nickel | | | | While reviewing the anticipated new projects from |
| and 7.5-percent molybdenum. To increase pitting | | | | the molybdenum mining sector, we foresee the |
| resistance, the manufacturers added up to | | | | high probability of supply inadequacy. Aside from |
| 0.5-percent nitrogen and three-percent | | | | China Moly's Sandaozhuang molybdenum mine, |
| manganese (for make the nitrogen more soluble). | | | | which the company hopes could produce 28,000 |
| As with all pioneering developments - and | | | | tonnes of molybdenum concentrate this year and |
| remember that R & D breakthroughs have taken | | | | perhaps grow by another 17 percent the following |
| place over a two-decade-plus period, | | | | year, there is a paucity of new molybdenum |
| manufacturers have re-designed their metallurgical | | | | projects coming fully online before 2009. |
| composition to find the most encouraging | | | | Based upon China's voracious appetite for |
| percentages of nickel, chromium, molybdenum | | | | molybdenum - one research firm estimated |
| and nitrogen. The earlier stainless steels relied on | | | | compounded annual growth rate over the |
| higher nickel content and lesser percentages of | | | | previous five years at 17 percent, whatever |
| chromium and molybdenum. | | | | excess moly production comes from China Moly's |
| At first, conventional austenitic grades, such as | | | | mining efforts could very well be domestically |
| 316L, or high chromium-ferritic grades, were | | | | consumed. |
| utilized. Pitting struck down widespread use of the | | | | Future North American molybdenum producers |
| 316L series and was replaced by higher alloy | | | | may need to ramp up their projects to meet the |
| steels. For example, others, such as the 254 | | | | growing demand. During 2006, demand grew |
| SMO(R) stainless steel, began aggressively | | | | above the historical norm of four percent; most |
| replacing the copper alloy tubes and in some | | | | of the consumption came from China. This is |
| cases the 316L series. The 254 is comprised of | | | | unlikely to stagnate or decrease, and could |
| 20-percent chromium, 18-percent nickel, | | | | interfere with North American and European |
| 6.2-percent molybdenum and 0.20-percent | | | | consumption of molybdenum. |
| nitrogen. It has also offered a high level of | | | | Only one company is scheduled to commence |
| corrosion resistance at desalination plants without | | | | molybdenum mining in 2007, Roca Mines. Because |
| becoming cost-prohibitive. | | | | the company is limited to a small-mining permit, |
| The most significant breakthrough came after | | | | anticipated production could not exceed three |
| various stainless steels were tested at | | | | million pounds. By late 2008, or early 2009, |
| Scandinavian coastal reactors. In the Avesta | | | | Adanac Molybdenum hopes to commence its |
| paper, the failures of each lesser austenitic grade | | | | start-up efforts to reach eight-figure moly |
| were checked off. Significant deficiencies included | | | | production. Later, Blue Pearl Mining hopes to |
| insufficient stress corrosion cracking resistance | | | | commence high-grade molybdenum mining at the |
| and resistance to natural seawater. Even titanium | | | | Davidson deposit in British Columbia. Around this |
| tubing was used as an interim measure because it | | | | time, the Climax molybdenum mine could re-open |
| increased total heat transfer by 17 percent, but | | | | and begin production in Colorado. Moly Mines hopes |
| the metal failed to stand up to high velocity | | | | to begin production at the company's Spinifex |
| steam and suffered 'water droplet erosion.' | | | | project. Possibly, before the decade ends, Idaho |
| According to the study, "The only alloy fully | | | | General might commence operations in Nevada. |
| resistant to all test conditions was 654 SMO(R)." | | | | Perhaps before those 48 nuclear reactors come |
| The results at nuclear power plants in Finland and | | | | online, US Energy's Mt. Emmons deposit may be |
| Sweden, along the Baltic Sea, were astonishing! | | | | mined in Colorado. |
| Four important conclusions about this super alloy | | | | Many of these projects are subject to |
| were reached after the testing. | | | | environmental permitting and/or financing, putting |
| · Its corrosion resistance could cope with the | | | | any material amount of forecasted supply in |
| hostile environments existing inside condenser | | | | jeopardy. And this comes at a time when some |
| tubes of desalination plants and power plants. | | | | experts believe byproduct molybdenum |
| · Its corrosion resistance was good enough | | | | production at copper mines could be constrained. |
| to cop with many other hostile brine and | | | | There are many conditional requirements which |
| seawater environments. | | | | do not necessarily guarantee a reliable supply |
| · Its erosion resistance was advantageous | | | | from the new breed of primary moly producers. |
| where it was exposed to high velocity streams. | | | | We have witnessed comparable obstacles in the |
| · There was no concern about its heat | | | | uranium sector, which has since been |
| transfer characteristics. | | | | accompanied by a hyperbolic price rally in this |
| Nuclear Consumption of Molybdenum | | | | metal. |
| About 48 nuclear reactors are reportedly | | | | There could come a point in the molybdenum |
| scheduled for construction by 2013. It may be | | | | sector where the silvery white metal could mimic |
| possible that up to 100 could be constructed by | | | | such a breakout scenario. Nearly three years ago, |
| 2020, depending upon political and financial climates. | | | | featured a forecast of US$100/pound uranium. No |
| The largest number proceeding through the | | | | one believed that prediction at the time. On |
| proposed, planned or construction phases will be | | | | Friday, TradeTech announced a spot price of |
| located along coastal areas to service the most | | | | US$113/pound. |
| populated areas. The greatest numbers of new | | | | COPYRIGHT© 2007 by StockInterview, Inc. |
| constructions are expected from China, India, | | | | ALL RIGHTS RESERVED. |
| Japan, Russia, South Korea and Japan (and | | | | |